First Animated Appearance of Wonder Woman

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1972 Brady Kids Sat morning cartoon. Superfriends showed up a year later in 1973.

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Before Super Friends Superman and Wonder Woman guest stared on The Brady Kids along with Lone Ranger.

Batman & Robin along with Superman showed up on Sesame Street before Super Friends.

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Of course Superman had been animated since the 40s with his cartoons and then his Filmation cartoons in the 60s along with Batman at the same time.